中國粉體網訊 透明鐵電材料可以將光學功能與壓電效應耦合在一起，為光聲成像系統、透明壓電致動器、透明機器人等提供關鍵材料。然而，壓電性、透明性和居里溫度之間的相互制約關系使得制備同時具有高居里點、高透明度和高壓電性的鐵電材料非常困難，這阻礙了其在多功能耦合器件領域的應用。
近日，青島大學物理科學學院制備出Sm摻雜PIN-PMN-PT透明鐵電陶瓷。其居里溫度Tc~179 ℃、壓電系數d33~905 pC/N、電光系數r~814 pm/V、近紅外波段透光率63%，綜合性能優異。與PMN-PT基透明陶瓷（Tc約100℃）相比，PIN-PMN-PT透明陶瓷在壓電性能的溫度穩定性方面表現優異。并且基于該透明陶瓷的電光效應和壓電效應，實現了電光信息調制和能量轉換。相關成果以"Sm-doped PIN-PMN-PT transparent ceramics with high Curie temperature, good piezoelectricity, and excellent electro-optical properties"為題發表在ACS Applied Materials & Interfaces上。青島大學物理科學學院2019級碩士研究生鄭鳳基為該論文第一作者，青島大學張永成副教授為論文的通訊作者。
這一成果也是該團隊在前期關于高電光性能PMN-PT透明陶瓷(Advanced Optical Materials, 9, 2002139 (2021))和高壓電性能PMN-PT透明陶瓷（ACS Appl. Mater. Interfaces, 13, 54210-54216(2021)）研究基礎上取得的新進展。上述工作得到了國家自然科學基金、山東省自然科學基金的支持。
圖1. Sm摻雜PIN-PMN-PT陶瓷的照片及透光率曲線。
圖2.Sm摻雜PIN-PMN-PT透明陶瓷的鐵電、壓電、介電性能的溫度穩定性。
圖3.Sm摻雜PIN-PMN-PT透明陶瓷的電光性能。
圖4. PIN-PMN-PT透明鐵電陶瓷在電光調制和能量轉換中的應用。
論文鏈接
https://doi.org/10.1021/acsami.2c19865
近期相關論文：
1. Fengji Zheng, Xue Tian, Yongcheng Zhang*, et al. Sm-Doped PIN-PMN-PT Transparent Ceramics with High Curie Temperature, Good Piezoelectricity, and Excellent Electro-Optical Properties, ACS Appl. Mater. Interfaces, 15, 7053−7062 (2023).
2. Ze Fang, Xiaodong Jiang, Yongcheng Zhang*, et al. Ultra-transparent PMN-PT Electro-Optic Ceramics and its Application in Optical Communication, Advanced Optical Materials, 9, 2002139 (2021).
3. Peikun Yan, Yalin Qin*, Yongcheng Zhang*, Shujun Zhang*,et al. Highly Transparent Eu-Doped 0.72PMN-0.28PT Ceramics with Excellent Piezoelectricity,ACS Appl. Mater. Interfaces, 13,54210-54216(2021).
4. Kai Li, Enwei Sun*, Yongcheng Zhang*, Bin Yang,*et al. High piezoelectricity of Eu3+-doped Pb(Mg1/3Nb2/3)O3–0.25PbTiO3transparent ceramics, Journal of Materials Chemistry C, 9, 2426-2436, (2021)
5. Ze Fang, Xue Tian, Yongcheng Zhang*, et al. Enhanced piezoelectric properties of Sm3+-modified PMN-PT ceramics and their application in energy harvesting, Ceramics International, 48, 7550–7556 (2022)
6. Shuang Zhang, Yongcheng Zhang*, Wanneng Ye* et al. In situ TEM observations of growth mechanisms of PbO nanoparticles from a Sm-doped PMN-PT matrix.Nanoscale, 14, 13801–13811(2022).
7. Ying Zheng, Yongcheng Zhang*, Wanneng Ye*, et al. Sm-Doped (1-x)Pb(Mg1/3Nb2/3)O3-xPbTiO3 Nanostructures for Piezocatalytic Dye Degradation. ACS Appl. Nano Mater, 5(1) 277–287(2022).
8. Mingqiang Cheng, Erding Zhao, Yongcheng Zhang*, et al. Ferroelectric and electromechanical performance of diverse engineered states of Mn-doped 0.75Pb(Mg1/3Nb2/3)O3-0.25PbTiO3ceramics. Ceramics International, 47,18417–18423(2021)
來源：作者團隊
論文鏈接：https://doi.org/10.1021/acsami.2c19865
（中國粉體網編輯整理/山川）
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